Transition metal complexes of Cu(II), Ni(II), Co(II) and Fe(III) Containing Bidentate Schiff base, derived from the condensation of salicyladehyde and 2-aminophenol were synthesized and characterized by IR, UV- Vis., and some physical measurements. IR spectral studies show the binding sites of the Schiff base ligand with the metal ion. Molar conductance data and magnetic susceptibility measurements give evidence for monomeric and electrolytic nature of the complexes. Structural studies showed that Cu(II), Ni(II) and Co(II) ion complexes are tetrahedral and Fe(III) ion complex is octahedral.
Published in | Science Journal of Chemistry (Volume 3, Issue 6) |
DOI | 10.11648/j.sjc.20150306.12 |
Page(s) | 91-94 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
Copyright |
Copyright © The Author(s), 2015. Published by Science Publishing Group |
Transition Metal Complex, Bidentate Ligand, Schiff Base
[1] | A. D. McNaught and A. Wilkinson, “Compendium of Chemical Terminology”, IUPAC Publications, 1997. |
[2] | Neelima Mishra, KavitanPoonia and Dinesh Kuma, “An overview of biological aspects of Schiff base metal complexes”, International Journal of Advancements in Research & Technology, 2013; 2(8): 52-66. |
[3] | Price C, Elsegood M R J, Clegg W, Houlton A, “Directed metallation of adenine-N3via nucleobase–ligand conjugation”, Journal of the Chemical Society, Chemical Communications, 1995; 22: 2285-2286. |
[4] | Nath M., Saini P. K. and Kumar, A., “New di- and triorganotin (IV) complexes of tripodal Schiff base ligand containing three imidazole arms: Synthesis, structural characterization, biological activity and thermal studies”, Journal of Organometallic Chem, 2010; 625: 1353-1362. |
[5] | Cheng L., Tang J., Luo H. Jin X., Dai F. , Yang J., Qian Y., Li X., and Zhou B., “Antioxidant and antiproliferative activities of hydroxyl-substituted Schiff bases”, Bioorg. Med. Chem. Lett., 2010; 20: 2417-2420. |
[6] | P. G. Cozzi, “Metal–Salen Schiff base complexes in catalysis: practical aspects”, Chem. Soc. Rev., 2004; 33: 410-421. |
[7] | D. Lednicer. “The Organic Chemistry of Drug Synthesis”, Vol-III, Wiley Interscience Publication, New York, 1984; 90: 283. |
[8] | Jarrahpour A. A. and Motamedifar M, Pakshir K., “Synthesis of novel azo Schiff bases and their antibacterial and antifungal activities”, Molecules, 2004; 9: 815-824. |
[9] | M. M. Haque, Md. Kudrat-E-Zahan Laila Arjuman Banu, Md. Shariful Islam and M. S. Islam, “Synthesis and Characterization with Antineoplastic, Bio-Chemical, Cytotoxic and Antimicrobial studies of Schiff Base Cu(II) ion Complexes”, Bioinorg. Chem. Appl., 2015; http://dx.doi.org/10.1155/2015/923087. |
[10] | Md. Kudrat-E-Zahan, M. S. Islam and Md. Abul Bashar. “Synthesis, Characterization and antimicrobial activity of Some Metal Complexes of Mn(II), Fe(III) Co(II), Ni(II), Cu(II) and Sb(III) Containing Bidentate Schiff base of SMDTC”, Rus. J. gen Chem., 2015; 85 (3): 667-672. |
[11] | Md.Kudrat-E-Zahan and M. S. Islam. “Synthesis, Characterization and Antimicrobial activity of Some Metal Complexes of Cu(II), Ni(II), Zn(II), Pb(II),Co(II), Mn(II) and U(VI) Containing Bidentate Schiff base of [S-methyl-3-(4-methoxybenzylidine) dithiocarbazate]”, Rus. J. gen Chem., 2015; 85 (4): 979-983. |
[12] | Md. Kudrat-E-Zahan, Md. Abdul Alim Al-Bari, Md. Abul Bashar , Laila Arjuman Banu, M. M. Haque and M. Saidul Islam, “Synthesis, Characterization and Biological Activity of Fe(III) Complexes with tartaric acid/succinic acid and heterocyclic amines”, International Journal of Materials Chemistry and Physics, 2015; 1(1): 82-85. |
[13] | Gagi Tauhidur Rahman, A. B. M. Nazmul Islam, M. M. Haque, Md. Kudrat-E-Zahan. Investigation on Antimicrobial Activity of Newly Synthesized Mixed Ligand Ni(II) Ion Complexes, International Journal of Materials Chemistry and Physics, 2015; 1(2): 207-211. |
[14] | Md. Kudrat-E-Zahan, Md. Masuqul Haque, Lokonuzzaman Ahmmed, M. Sher Ali, Md. Saidul Islam, Studies on the Mixed Ligand Complexes of Co(II), Ni(II) and Cu(II) with Phthalimide and Heterocyclic Amines, International Journal of Materials Science and Applications. 2015; 4(2): 120-123. |
[15] | Md. Sher Ali, Md. Kudrat-E-Zahan, Md. Masuqul Haque, Md. Abdul Alim, Md. Moffaserul Alam, Jesmin Ara Shompa, M. S. Islam. Mixed Ligand Complexes of Co(II) and Ni(II) Containing Organic Acids and Amine Bases as Primary and Secondary Ligands. International Journal of Materials Science and Applications. 2015; 4(4): 225-228. |
[16] | W. J. Geary, “The use of conductivity measurements in organic solvents for the characterization of coordination compounds,” Coordination Chemistry Reviews, 1971; 7(1): 81–122. |
[17] | B. N. Figgis and J. Lewis, “The magnetic properties of transition metal complexes,” Prog. Inorg. Chem., 1964; 6: 73. |
APA Style
Gagi Tauhidur Rahman, Md. Kudrat-E-Zahan, M. M. Haque, Md. Mofasserul Alam, Md. Akhter Farooque. (2015). Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method. Science Journal of Chemistry, 3(6), 91-94. https://doi.org/10.11648/j.sjc.20150306.12
ACS Style
Gagi Tauhidur Rahman; Md. Kudrat-E-Zahan; M. M. Haque; Md. Mofasserul Alam; Md. Akhter Farooque. Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method. Sci. J. Chem. 2015, 3(6), 91-94. doi: 10.11648/j.sjc.20150306.12
AMA Style
Gagi Tauhidur Rahman, Md. Kudrat-E-Zahan, M. M. Haque, Md. Mofasserul Alam, Md. Akhter Farooque. Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method. Sci J Chem. 2015;3(6):91-94. doi: 10.11648/j.sjc.20150306.12
@article{10.11648/j.sjc.20150306.12, author = {Gagi Tauhidur Rahman and Md. Kudrat-E-Zahan and M. M. Haque and Md. Mofasserul Alam and Md. Akhter Farooque}, title = {Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method}, journal = {Science Journal of Chemistry}, volume = {3}, number = {6}, pages = {91-94}, doi = {10.11648/j.sjc.20150306.12}, url = {https://doi.org/10.11648/j.sjc.20150306.12}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20150306.12}, abstract = {Transition metal complexes of Cu(II), Ni(II), Co(II) and Fe(III) Containing Bidentate Schiff base, derived from the condensation of salicyladehyde and 2-aminophenol were synthesized and characterized by IR, UV- Vis., and some physical measurements. IR spectral studies show the binding sites of the Schiff base ligand with the metal ion. Molar conductance data and magnetic susceptibility measurements give evidence for monomeric and electrolytic nature of the complexes. Structural studies showed that Cu(II), Ni(II) and Co(II) ion complexes are tetrahedral and Fe(III) ion complex is octahedral.}, year = {2015} }
TY - JOUR T1 - Structural Analysis of Newly Synthesized NO Donor Schiff Base Complexes of Cu(II), Ni(II), Co(II) and Fe(III) Metal Ions by Conventional Method AU - Gagi Tauhidur Rahman AU - Md. Kudrat-E-Zahan AU - M. M. Haque AU - Md. Mofasserul Alam AU - Md. Akhter Farooque Y1 - 2015/10/19 PY - 2015 N1 - https://doi.org/10.11648/j.sjc.20150306.12 DO - 10.11648/j.sjc.20150306.12 T2 - Science Journal of Chemistry JF - Science Journal of Chemistry JO - Science Journal of Chemistry SP - 91 EP - 94 PB - Science Publishing Group SN - 2330-099X UR - https://doi.org/10.11648/j.sjc.20150306.12 AB - Transition metal complexes of Cu(II), Ni(II), Co(II) and Fe(III) Containing Bidentate Schiff base, derived from the condensation of salicyladehyde and 2-aminophenol were synthesized and characterized by IR, UV- Vis., and some physical measurements. IR spectral studies show the binding sites of the Schiff base ligand with the metal ion. Molar conductance data and magnetic susceptibility measurements give evidence for monomeric and electrolytic nature of the complexes. Structural studies showed that Cu(II), Ni(II) and Co(II) ion complexes are tetrahedral and Fe(III) ion complex is octahedral. VL - 3 IS - 6 ER -