The synthesis of nano-CaO can be produced from natural resources, chemical compounds, and waste containing calcium such as clamshell (Geloine sp.). The research aims to study the effect of temperature and reaction time (sol formation) on the yield of nano-CaO after the calcination process and to characterize the Ca(OH)2 and nano-CaO obtained. The result shows that clamshell (Geloine sp.) waste can be used as raw material for the synthesis of nano-CaO using the sol-gel method. The main factor in the synthesis of nano-CaO by sol-gel method is sol formation from the calcium precursor with hydrochloric acid to form calcium chloride. The optimum temperature of sol formation is at the temperature of 90 – 100°C for 60 minutes of reaction time with a yield of nano-CaO of 11.34 – 12%. The optimum reaction time of gel formation is the reaction time of 90 minutes at a temperature of 100°C with a yield of nano-CaO of 14.5%. The yield of CaO decreases after the reaction time of 90 minutes. It is can be concluded that the optimum conditions for gel formation are a temperature of 100°C and a reaction time of 90 minutes. The nano-CaO can be used for any purpose, such as an additive to body soap because of its antimicrobial activity.
| Published in | American Journal of Chemical Engineering (Volume 12, Issue 1) |
| DOI | 10.11648/ajche.20241201.11 |
| Page(s) | 1-5 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Nano-CaO, Clamshell, Sol-Gel Method
| [1] | L. Habte, N. Shiferaw, D. Mulatu, T. Thenepalli, R. Chilakala, and J. W. Ahn, “Synthesis of nano-calcium oxide from waste eggshell by sol-gel method,” Sustainability (Switzerland), vol. 11, no. 11, Jun. 2019, doi: 10.3390/su11113196. |
| [2] | J. O. Masime, E. O. Ogur, B. N. Mbatia, A. O. Aluoch, and G. Otieno, “Characterization of Eggshells Nanocatalyst: Synthesized by Bottom-Up Technology,” Walisongo Journal of Chemistry, vol. 5, no. 2, pp. 202–211, Dec. 2022, doi: 10.21580/wjc.v5i2.13434. |
| [3] | R. G. Jalu, T. A. Chamada, and D. R. Kasirajan, “Calcium oxide nanoparticles synthesis from hen eggshells for removal of lead (Pb(II)) from aqueous solution,” Environmental Challenges, vol. 4, Aug. 2021, doi: 10.1016/j.envc.2021.100193. |
| [4] | N. Gultekin and E. Kucukates, “Evaluation of Antimicrobial Activity of Scallop Shell Powder Against Staphylococci Species and Gram Negative Bacteria Isolated From Patients Intensive Care Units,” Biomed J Sci Tech Res, vol. 13, no. 4, 2019, doi: 10.26717/bjstr.2019.13.002445. |
| [5] | A. Ma’ruf, C. Khotimah, and N. Ngafwan, “Synthesis of nano-CaO from clamshell (Geloina sp.) using papaya latex as biocatalyst,” Chemical Papers, vol. 77, no. 12, pp. 7969–7975, Dec. 2023, doi: 10.1007/s11696-023-03068-9. |
| [6] | N. Andarini, R. S. Farida, and T. Haryati, “The Effect of Different Precursor Concentration on The Synthesis of CaO Nanoparticles with Coprecipitation Methods for Palm Oil Transesterification Catalysis,” Reaktor, vol. 21, no. 2, pp. 45–51, Aug. 2021, doi: 10.14710/reaktor.21.2.45-51. |
| [7] | E. E. Khine et al., “Synthesis and characterization of calcium oxide nanoparticles for CO2 capture,” Journal of Nanoparticle Research, vol. 24, no. 7, Jul. 2022, doi: 10.1007/s11051-022-05518-z. |
| [8] | Z. X. Tang, D. Claveau, R. Corcuff, K. Belkacemi, and J. Arul, “Preparation of nano-CaO using thermal-decomposition method,” Mater Lett, vol. 62, no. 14, pp. 2096–2098, May 2008, doi: 10.1016/j.matlet.2007.11.053. |
| [9] | A. Roy and J. Bhattacharya, “Microwave-assisted synthesis and characterization of CaS nanoparticles,” Int J Nanosci, vol. 10, no. 3, Oct. 2011, doi: 10.1142/S0219581X12500275. |
| [10] | M. Can, A. Helvaci, Z. Yazici, S. Akpınar, and Y. Özdemir, “Microwave Assisted Calcination of Colemanite Powders,” International Journal of Metallurgical & Materials Engineering, vol. 2, no. 2, Dec. 2016, doi: 10.15344/2455-2372/2016/129. |
| [11] | F. A. Mostafa, A. N. Gad, A. A. M. Gaber, and A. M. A. Abdel-Wahab, “Preparation, Characterization and Application of Calcium Oxide Nanoparticles from Waste Carbonation Mud in Clarification of Raw Sugar Melt,” Sugar Tech, vol. 25, no. 2, pp. 331–338, Apr. 2023, doi: 10.1007/s12355-022-01150-2. |
| [12] | C. W. Loy et al., “Effects of Calcination on the Crystallography and Nonbiogenic Aragonite Formation of Ark Clam Shell under Ambient Condition,” Advances in Materials Science and Engineering, vol. 2016, 2016, doi: 10.1155/2016/2914368. |
| [13] | Y. Tang, Y. Yang, H. Liu, T. Yan, and Z. Zhang, “Preparation of nano-CaO and catalyzing tri-component coupling transesterification to produce biodiesel,” Inorganic and Nano-Metal Chemistry, vol. 50, no. 7, pp. 501–507, 2020, doi: 10.1080/24701556.2020.1720726. |
| [14] | S. Ranghar, P. Sirohi, P. Verma, and V. Agarwal, “Nanoparticle-based drug delivery systems: Promising approaches against infections,” Brazilian Archives of Biology and Technology, vol. 57, no. 2, pp. 209–222, 2014, doi: 10.1590/S1516-89132013005000011. |
| [15] | M. Sadeghi and M. Hassan Husseini, “A Novel Method for the Synthesis of CaO Nanoparticle for the Decomposition of Sulfurous Pollutant,” 2013. |
| [16] | S. Abraham and V. P. Sarathy, “Research Article Biomedical Applications of Calcium Oxide Nanoparticles - A Spectroscopic Study,” Int. J. Pharm. Sci. Res., vol. 49, no. 1, pp. 121–125, 2018. |
| [17] | A. Roy, S. S. Gauri, M. Bhattacharya, and J. Bhattacharya, “Antimicrobial activity of CaO nanoparticles,” J Biomed Nanotechnol, vol. 9, no. 9, pp. 1570–1578, 2013, doi: 10.1166/jbn.2013.1681. |
APA Style
Ma’ruf, A., Prananda, A. N. (2024). Synthesis and Characterization of Nano-CaO from Clamshell (Geloine sp.) Using Sol-Gel Method. American Journal of Chemical Engineering, 12(1), 1-5. https://doi.org/10.11648/ajche.20241201.11
ACS Style
Ma’ruf, A.; Prananda, A. N. Synthesis and Characterization of Nano-CaO from Clamshell (Geloine sp.) Using Sol-Gel Method. Am. J. Chem. Eng. 2024, 12(1), 1-5. doi: 10.11648/ajche.20241201.11
AMA Style
Ma’ruf A, Prananda AN. Synthesis and Characterization of Nano-CaO from Clamshell (Geloine sp.) Using Sol-Gel Method. Am J Chem Eng. 2024;12(1):1-5. doi: 10.11648/ajche.20241201.11
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Download@article{10.11648/ajche.20241201.11,
author = {Anwar Ma’ruf and Arief Nur’ari Prananda},
title = {Synthesis and Characterization of Nano-CaO from Clamshell (Geloine sp.) Using Sol-Gel Method},
journal = {American Journal of Chemical Engineering},
volume = {12},
number = {1},
pages = {1-5},
doi = {10.11648/ajche.20241201.11},
url = {https://doi.org/10.11648/ajche.20241201.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.ajche.20241201.11},
abstract = {The synthesis of nano-CaO can be produced from natural resources, chemical compounds, and waste containing calcium such as clamshell (Geloine sp.). The research aims to study the effect of temperature and reaction time (sol formation) on the yield of nano-CaO after the calcination process and to characterize the Ca(OH)2 and nano-CaO obtained. The result shows that clamshell (Geloine sp.) waste can be used as raw material for the synthesis of nano-CaO using the sol-gel method. The main factor in the synthesis of nano-CaO by sol-gel method is sol formation from the calcium precursor with hydrochloric acid to form calcium chloride. The optimum temperature of sol formation is at the temperature of 90 – 100°C for 60 minutes of reaction time with a yield of nano-CaO of 11.34 – 12%. The optimum reaction time of gel formation is the reaction time of 90 minutes at a temperature of 100°C with a yield of nano-CaO of 14.5%. The yield of CaO decreases after the reaction time of 90 minutes. It is can be concluded that the optimum conditions for gel formation are a temperature of 100°C and a reaction time of 90 minutes. The nano-CaO can be used for any purpose, such as an additive to body soap because of its antimicrobial activity.},
year = {2024}
}
TY - JOUR T1 - Synthesis and Characterization of Nano-CaO from Clamshell (Geloine sp.) Using Sol-Gel Method AU - Anwar Ma’ruf AU - Arief Nur’ari Prananda Y1 - 2024/02/01 PY - 2024 N1 - https://doi.org/10.11648/ajche.20241201.11 DO - 10.11648/ajche.20241201.11 T2 - American Journal of Chemical Engineering JF - American Journal of Chemical Engineering JO - American Journal of Chemical Engineering SP - 1 EP - 5 PB - Science Publishing Group SN - 2330-8613 UR - https://doi.org/10.11648/ajche.20241201.11 AB - The synthesis of nano-CaO can be produced from natural resources, chemical compounds, and waste containing calcium such as clamshell (Geloine sp.). The research aims to study the effect of temperature and reaction time (sol formation) on the yield of nano-CaO after the calcination process and to characterize the Ca(OH)2 and nano-CaO obtained. The result shows that clamshell (Geloine sp.) waste can be used as raw material for the synthesis of nano-CaO using the sol-gel method. The main factor in the synthesis of nano-CaO by sol-gel method is sol formation from the calcium precursor with hydrochloric acid to form calcium chloride. The optimum temperature of sol formation is at the temperature of 90 – 100°C for 60 minutes of reaction time with a yield of nano-CaO of 11.34 – 12%. The optimum reaction time of gel formation is the reaction time of 90 minutes at a temperature of 100°C with a yield of nano-CaO of 14.5%. The yield of CaO decreases after the reaction time of 90 minutes. It is can be concluded that the optimum conditions for gel formation are a temperature of 100°C and a reaction time of 90 minutes. The nano-CaO can be used for any purpose, such as an additive to body soap because of its antimicrobial activity. VL - 12 IS - 1 ER -
Chemical Engineering Department, Faculty of Engineering and Science, Universitas Muhammadiyah Purwokerto, Purwokerto, Indonesia
